SYNTHESIS AND STRUCTURE OF TWO NOVEL METAL-ORGANIC FRAMEWORKS BASED ON CLUSTER ANIONS [Re6Se8(CN)6]4–, CATIONS Tb3+, AND ISONICOTINATE ANIONS Full article
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2020, Volume: 61, Number: 10, Pages: 1630-1638 Pages count : 9 DOI: 10.1134/s0022476620100169 | ||||||
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Abstract:
The interaction of cluster anions [Re6Se8(CN)6]4– with cations Tb3+ in the presence of 4-cyanopyridine in aqueous solution is studied. Two novel framework compounds (K[{Tb3(H2O)2}(ina)2}{Re6Se8(CN)6}2]·7H2O (1) and [{Tb4(OH)4(μ-ina)2(ina)2(H2O)4}{Re6Se8(CN)6}]·7.5H2O (2) where ina = isonicotinic acid anion) are prepared by the solvothermal synthesis as a result of 4-cyanopyridine hydrolysis to produce isonicotinic acid and subsequent self-assembly in solution with cations Tb3+ and a presynthesized cluster anion [Re6Se8(CN)6]4–.
Cite:
Litvinova Y.M.
, Gayfulin Y.M.
, Samsonenko D.G.
, Dorovatovsky P.V.
, Lazarenko V.A.
, Mironov Y.V.
SYNTHESIS AND STRUCTURE OF TWO NOVEL METAL-ORGANIC FRAMEWORKS BASED ON CLUSTER ANIONS [Re6Se8(CN)6]4–, CATIONS Tb3+, AND ISONICOTINATE ANIONS
Journal of Structural Chemistry. 2020. V.61. N10. P.1630-1638. DOI: 10.1134/s0022476620100169 WOS Scopus РИНЦ OpenAlex
SYNTHESIS AND STRUCTURE OF TWO NOVEL METAL-ORGANIC FRAMEWORKS BASED ON CLUSTER ANIONS [Re6Se8(CN)6]4–, CATIONS Tb3+, AND ISONICOTINATE ANIONS
Journal of Structural Chemistry. 2020. V.61. N10. P.1630-1638. DOI: 10.1134/s0022476620100169 WOS Scopus РИНЦ OpenAlex
Original:
Литвинова Ю.М.
, Гайфулин Я.М.
, Самсоненко Д.Г.
, Дороватовский П.В.
, Лазаренко В.А.
, Миронов Ю.В.
Синтез и строение двух новых металл-органических каркасов на основе кластерных анионов [Re6Se8(CN)6]4–, катионов Tb3+ и изоникотинат-анионов
Журнал структурной химии. 2020. Т.61. №10. С.1715-1723. DOI: 10.26902/jsc_id61863 РИНЦ OpenAlex
Синтез и строение двух новых металл-органических каркасов на основе кластерных анионов [Re6Se8(CN)6]4–, катионов Tb3+ и изоникотинат-анионов
Журнал структурной химии. 2020. Т.61. №10. С.1715-1723. DOI: 10.26902/jsc_id61863 РИНЦ OpenAlex
Dates:
| Submitted: | Apr 23, 2020 |
| Accepted: | May 8, 2020 |
| Published online: | Oct 13, 2020 |
Identifiers:
| Web of science: | WOS:000598775100016 |
| Scopus: | 2-s2.0-85106784940 |
| Elibrary: | 46791689 |
| OpenAlex: | W3110797935 |