Synthesis and crystal structure of new coordination polymers based on sodium aqua complexes and macrocyclic cavitand cucurbit[6]uril Full article
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Output data | Year: 2020, Volume: 69, Number: 11, Pages: 2113-2120 Pages count : 8 DOI: 10.1007/s11172-020-3008-z | ||
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Abstract:
The crystals of the compounds [Na4(H2O)14CB[6]](bdc)2 · 13H2O (1) and [Na6(H2O)19CB[6]]-(bdc)3 ·15H2O (2) were obtained by heating an aqueous solution of sodium terephthalate (Na2bdc) and cucurbit[6]uril (CB[6]). According to the single-crystal X-ray diffraction data, the sodium aqua complexes and cucurbit[6]uril molecules form chains (in structure 1) and layered metal-organic frameworks (in structure 2). The structures of the sodium aqua complexes [Na3(H2O)10]3+ in 1 and [Na6(H2O)19]3+ in 2 have been previously unknown. When submitted to ultraviolet radiation, crystals of 1 and 2 exhibit luminescence with an emission maximum at 428 and 434 nm, respectively.
Cite:
Andrienko I.V.
, Kovalenko E.A.
, Samsonenko D.G.
, Fedin V.P.
Synthesis and crystal structure of new coordination polymers based on sodium aqua complexes and macrocyclic cavitand cucurbit[6]uril
Russian Chemical Bulletin. 2020. V.69. N11. P.2113-2120. DOI: 10.1007/s11172-020-3008-z WOS Scopus РИНЦ OpenAlex
Synthesis and crystal structure of new coordination polymers based on sodium aqua complexes and macrocyclic cavitand cucurbit[6]uril
Russian Chemical Bulletin. 2020. V.69. N11. P.2113-2120. DOI: 10.1007/s11172-020-3008-z WOS Scopus РИНЦ OpenAlex
Original:
Андриенко И.В.
, Коваленко Е.А.
, Самсоненко Д.Г.
, Федин В.П.
Синтез и кристаллическая структура новых координационных полимеров на основе аквакомплексов натрия и макроциклического кавитанда кукурбит[6]урила
Известия Академии наук. Серия химическая. 2020. №11. С.2113-2120. РИНЦ
Синтез и кристаллическая структура новых координационных полимеров на основе аквакомплексов натрия и макроциклического кавитанда кукурбит[6]урила
Известия Академии наук. Серия химическая. 2020. №11. С.2113-2120. РИНЦ
Dates:
| Submitted: | Feb 14, 2020 |
| Accepted: | Jul 6, 2020 |
| Published online: | Dec 4, 2020 |
Identifiers:
| Web of science: | WOS:000596085400010 |
| Scopus: | 2-s2.0-85097078213 |
| Elibrary: | 45110969 |
| OpenAlex: | W3110981948 |