CRYSTAL STRUCTURE OF METAL-ORGANIC FRAMEWORKS OBTAINED FROM A HETEROMETALLIC PIVALATE COMPLEX [Li2Zn2(py)2(piv)6]

CRYSTAL STRUCTURE OF METAL-ORGANIC FRAMEWORKS OBTAINED FROM A HETEROMETALLIC PIVALATE COMPLEX [Li2Zn2(py)2(piv)6] Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2020, Volume: 61, Number: 12, Pages: 1957-1964 Pages count : 8 DOI: 10.1134/s0022476620120148

Authors

Sapianik A.A. ^1,2 , Dudko E.R. ^1,2 , Samsonenko D.G. ^1,2 , Fedin V.P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

In the interaction of the heterometallic complex [Li2Zn2(py)2(piv)6] (piv– is the pivalate anion, py is pyridine) with 2,5-dibromoterephthalic acid (H2Br2-bdc) or 9,10-anthracenedicarboxylic acid (H2adc), two coordination polymers [Li(DMF)(HBr2-bdc)] (1) and (Me2NH2)[Zn(Hadc) (adc)]·DMF·H2O (2) are obtained. During the synthesis, the initial tetranuclear heterometallic fragment is completely fragmentated. When the same complex interacts with nitroterephthalic acid (H2NO2-bdc), a heterometallic metal-organic framework (Me2NH2)[LiZn(NO2- bdc)2]·DMF (3) is formed. Resulting coordination polymer 3 has a three-dimensional porous structure; binuclear heterometallic carboxylate moieties {LiZn(COO)3} act as secondary building blocks.

Sapianik A.A. , Dudko E.R. , Samsonenko D.G. , Fedin V.P.
CRYSTAL STRUCTURE OF METAL-ORGANIC FRAMEWORKS OBTAINED FROM A HETEROMETALLIC PIVALATE COMPLEX [Li2Zn2(py)2(piv)6]
Journal of Structural Chemistry. 2020. V.61. N12. P.1957-1964. DOI: 10.1134/s0022476620120148 WOS Scopus Scopus OpenAlex

Сапьяник А.А. , Дудко Е.Р. , Самсоненко Д.Г. , Федин В.П.
Кристаллическая структура металл-органических координационных полимеров, полученных из гетерометаллического пивалатного комплекса [Li2Zn2(py)2(piv)6]
Журнал структурной химии. 2020. Т.61. №12. С.2064-2071. DOI: 10.26902/jsc_id66720 OpenAlex

Submitted:	May 18, 2020
Accepted:	May 21, 2020
Published online:	Dec 25, 2020

Web of science:	WOS:000602178800014
Scopus:	2-s2.0-85098050992 \| 2-s2.0-85088642910
OpenAlex:	W3118029267

DB	Citing
OpenAlex	3
Scopus	3 5
Web of science	4