Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers Full article
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Output data | Year: 2020, Volume: 69, Number: 7, Pages: 1264-1271 Pages count : 8 DOI: 10.1007/s11172-020-2896-2 | ||||
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Abstract:
The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.
Cite:
Litvinova Y.M.
, Gayfulin Y.M.
, Samsonenko D.G.
, Mironov Y.V.
Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers
Russian Chemical Bulletin. 2020. V.69. N7. P.1264-1271. DOI: 10.1007/s11172-020-2896-2 WOS Scopus Scopus OpenAlex
Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers
Russian Chemical Bulletin. 2020. V.69. N7. P.1264-1271. DOI: 10.1007/s11172-020-2896-2 WOS Scopus Scopus OpenAlex
Original:
Литвинова Ю.М.
, Гайфулин Я.М.
, Самсоненко Д.Г.
, Миронов Ю.В.
Металл-органические каркасы на основе кластерных анионов [Re6Se8(CN)6]4–, катионов Yb3+ и тиофен-2,5-дикарбоксилатных линкеров
Известия Академии наук. Серия химическая. 2020. №7. С.1264-1271. РИНЦ
Металл-органические каркасы на основе кластерных анионов [Re6Se8(CN)6]4–, катионов Yb3+ и тиофен-2,5-дикарбоксилатных линкеров
Известия Академии наук. Серия химическая. 2020. №7. С.1264-1271. РИНЦ
Dates:
| Submitted: | Sep 30, 2019 |
| Accepted: | Mar 13, 2020 |
| Published online: | Sep 2, 2020 |
Identifiers:
| Web of science: | WOS:000565770300005 |
| Scopus: | 2-s2.0-85090147801 | 2-s2.0-85088239476 |
| OpenAlex: | W3081902803 |