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0D to 3D Coordination Assemblies Engineered on Silver(I) Salts and 2‐(Alkylsulfanyl)azine Ligands: Crystal Structures, Dual Luminescence, and Cytotoxic Activity Full article

Journal European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682
Output data Year: 2020, Volume: 2020, Number: 17, Pages: 1635-1644 Pages count : 10 DOI: 10.1002/ejic.202000109
Authors Rogovoy Maxim I. 1 , Frolova Tatiana S. 2,3 , Samsonenko Denis G. 1 , Berezin Alexey S. 1 , Bagryanskaya Irina Yu. 4 , Nedolya Nina A. 5 , Tarasova Olga A. 5 , Fedin Vladimir P. 1 , Artem'ev Alexander V. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry SB RAS, 3, Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation
2 Novosibirsk State University, 2, Pirogova Str., 630090 Novosibirsk, Russian Federation
3 Institute of Cytology and Genetics SB RAS, 10, Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation
4 N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, 9, Acad. Lavrentiev Ave., 630090 Novosibirsk, Russian Federation
5 A. E. Favorsky Irkutsk Institute of Chemistry SB RAS, 1, Favorsky st., 664033 Irkutsk, Russian Federation

Abstract: The potential of 2-(alkylsulfanyl)azine ligands for crystal engineering of functional Ag(I) complexes has been firstly demonstrated. The reaction of AgNO3, AgClO4 and AgOTf with 2-(alkylsulfanyl)pyridines, -pyrimidines, and -quinolines gives a series of new Ag(I) compounds that range from mono- and dinuclear complexes to chain (1D), layered (2D) and framework (3D) coordination polymers (CPs). 2-(Alkylsulfanyl)pyridines and -pyrimidines, depending on the reaction conditions, are assembled either into molecular complexes or CPs, while 2-(alkylsulfanyl)quinolines afford dinuclear complexes exclusively. The most of compounds engineered feature site-specific interactions such as Ag···Ag, Ag···O, and Ag···S ones. The 2-(methylsulfanyl)quinoline (2-MeSQn) complex, [Ag2(2-MeSQn)2(NO3)2], displays room temperature intraligand (IL) phosphorescence, while the 2-(methylsulfanyl)pyridine-derived CPs emit dual luminescence expressed by IL fluorescence and phosphorescence. Moreover, cytotoxic activity of the compounds synthesized has been evaluated against hTERT lung fibroblasts, HeLa, MCF7, HepG2 and A549 cancer cells.
Cite: Rogovoy M.I. , Frolova T.S. , Samsonenko D.G. , Berezin A.S. , Bagryanskaya I.Y. , Nedolya N.A. , Tarasova O.A. , Fedin V.P. , Artem'ev A.V.
0D to 3D Coordination Assemblies Engineered on Silver(I) Salts and 2‐(Alkylsulfanyl)azine Ligands: Crystal Structures, Dual Luminescence, and Cytotoxic Activity
European Journal of Inorganic Chemistry. 2020. V.2020. N17. P.1635-1644. DOI: 10.1002/ejic.202000109 WOS Scopus OpenAlex
Dates:
Submitted: Feb 4, 2020
Published online: Mar 26, 2020
Identifiers:
Web of science: WOS:000527685600001
Scopus: 2-s2.0-85083663579
OpenAlex: W3013810754
Citing:
DB Citing
OpenAlex 31
Scopus 26
Web of science 31
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