Urotropine as a ligand for the efficient synthesis of metal-organic frameworks

Urotropine as a ligand for the efficient synthesis of metal-organic frameworks Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2020, Volume: 69, Number: 3, Pages: 461-469 Pages count : 9 DOI: 10.1007/s11172-020-2785-8

Authors

Sapchenko S.A. ^1,2,3 , Barsukova M.O. ^1,2 , Nokhrina T.V. ^1,2 , Kovalenko K.A. ^1,2 , Samsonenko D.G. ^1,2 , Dybtsev D.N. ^1,2 , Fedin V.P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation
3	School of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK

Urotropine is a cheap and promising ligand for the synthesis of metal-organic frameworks containing uncoordinated nitrogen atoms. The reactions between urotropine, dicarboxylic acids, and zinc(II) or cobalt(II) salts were studied. The optimization of the reaction conditions allows the synthesis of three urotropine-containing metal-organic frameworks, [Zn(ur)(abdc)]• •DMF•H2O (1, ur is urotropine, abdc2− is 4,4´-diazobiphenyldicarboxylate, DMF is N,N-dimethylformamide), (CH3ur)[NaCo(dmf)2(bptc)] (2, CH3ur+ is N-methylhexa methyl enetetrammonium, bptc4− is 2,2´,4,4´-biphenyltetracarboxylate), and [Co4(dmf)(ur)2(ndc)4]•5DMF (3, ndc2− is 2,6-naphthalenedicarboxylate). These compounds were structurally characterized and their thermal and adsorption properties were studied. In the three compounds, urotropine performs diff erent functions, acting as a monodentate ligand (compound 1), a bidentate ligand (compound 3), or a methylammonium counterion (compound 2).

Sapchenko S.A. , Barsukova M.O. , Nokhrina T.V. , Kovalenko K.A. , Samsonenko D.G. , Dybtsev D.N. , Fedin V.P.
Urotropine as a ligand for the efficient synthesis of metal-organic frameworks
Russian Chemical Bulletin. 2020. V.69. N3. P.461-469. DOI: 10.1007/s11172-020-2785-8 WOS Scopus OpenAlex

Сапченко С.А. , Барсукова М.О. , Нохрина Т.В. , Коваленко К.А. , Самсоненко Д.Г. , Дыбцев Д.Н. , Федин В.П.
Уротропин в качестве лиганда для эффективного синтеза металл-органических координационных полимеров
Известия Академии наук. Серия химическая. 2020. №3. С.461-469.

Submitted:	Sep 26, 2019
Accepted:	Dec 16, 2019
Published online:	Apr 8, 2020

Web of science:	WOS:000524864600005
Scopus:	2-s2.0-85083312083
OpenAlex:	W3015753306

DB	Citing
OpenAlex	7
Scopus	7
Web of science	7