Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes

Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes Full article

Journal

Polyhedron
ISSN: 1873-3719 , E-ISSN: 0277-5387

Output data

Year: 2020, Volume: 177, Article number : 114330, Pages count : 13 DOI: 10.1016/j.poly.2019.114330

Tags

Benzotriazole, Cadmium, Silver, Coordination polymers, Crystal structure

Authors

Marchenko Roman D. ¹ , Lysova Anna A. ^2,3 , Samsonenko Denis G. ^2,3 , Dybtsev Danil N. ^2,3 , Potapov Andrei S. ^1,2

Affiliations

1	Kizhner Research Center Tomsk Polytechnic University, 30 Lenin Ave., 634050 Tomsk, Russia
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia
3	Novosibirsk State University, 2 Pirogov Str., 630090 Novosibirsk, Russia

A series of bis(benzo-1,2,3-triazolyl)alkanes were prepared by the reaction of 1,2,3-benzotriazole with the corresponding dibromoalkanes. Individual isomers of these flexible polydentate ligands were separated by selective copper(II) chloride complex formation. Seven new coordination compounds of 1,3-bis(benzo-1,2,3-triazol-1-yl)propane (L3), 1,4-bis(benzo-1,2,3-triazol-1-yl)butane (L4) and 1,6-bis(benzo-1,2,3-triazol-1-yl)hexane (L6) with cadmium(II) or silver(I) nitrates were prepared, characterized by single crystal X-ray diffraction, IR spectroscopy, thermogravimetric analysis and luminescence studies. It was found that depending on the solvent used, cadmium(II) nitrate forms discrete binuclear complex with the ligand L3 in acetone and 1D coordination polymer in acetonitrile. Ligands L4 and L6 with longer linkers formed 2D coordination polymers with silver nitrate both in acetone and acetonitrile. Silver coordination polymer with L6 demonstrated bactericidal effect towards Staphylococcus albus, Pseudomonas aeruginosa and Klebsiella pneumonia bacteria.

Marchenko R.D. , Lysova A.A. , Samsonenko D.G. , Dybtsev D.N. , Potapov A.S.
Synthesis, structural diversity, luminescent properties and antibacterial effects of cadmium(II) and silver(I) coordination compounds with bis(1,2,3-benzotriazol-1-yl)alkanes
Polyhedron. 2020. V.177. 114330 :1-13. DOI: 10.1016/j.poly.2019.114330 WOS Scopus OpenAlex

Submitted:	Sep 11, 2019
Accepted:	Dec 19, 2019
Published online:	Dec 23, 2019
Published print:	Jan 3, 2020

Web of science:	WOS:000518876600034
Scopus:	2-s2.0-85077316469
OpenAlex:	W2998202882

DB	Citing
OpenAlex	18
Scopus	18
Web of science	17