New one-, two-, and three-dimensional metal-organic frameworks based on magnesium(II): synthesis and structure

New one-, two-, and three-dimensional metal-organic frameworks based on magnesium(II): synthesis and structure Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2020, Volume: 69, Number: 2, Pages: 360-368 Pages count : 9 DOI: 10.1007/s11172-020-2768-9

Authors

Marakulin A.V. ^1,2 , Lysova A.A. ^1,2 , Samsonenko D.G. ^1,2 , Dorovatovskii P.V. ³ , Lazarenko V.A. ³ , Dybtsev D.N. ^1,2 , Fedin V.P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation
3	National Research Center "Kurchatov Institute", 1 ul. Akad. Kurchatova, 123182, Moscow, Russian Federation

Six new metal-organic frameworks based on magnesium(II) ions of various dimensionality were synthesized: chain-like [Mg(Hazdc)2(nmp)2] (1, H2azdc is 4,4′-azobenzenedicarboxylic acid, nmp is N-methylpyrrolidone), layered [Mg(H2btc)(nmp)2] (2, H4btc is 1,2,4,5-benzene-tetracarboxylic acid), [Mg3(sdc)3(def)4] •3DEF (3, H2sdc is 4,4’-stilbenedicarboxylic acid, def or DEF is N,N-diethylformamide), [Mg3(azdc)3(dma)4] • 3DMA (4, dma or DMA is N,N-di-methylacetamide), [Mg3(azdc)3(dmf)4] (5, dmf is N,N-dimethylformamide), and doubly-interpenetrated three-dimensional [Mg3(azdc)3(nmp)4] •NMP (6, NMP is N-methylpyrrolidone). According to the single-crystal X-ray dif raction data, compounds 1 and 2 are built from mononuclear carboxylate units {Mg(RCOOH)2(RCOO)2(nmp)2}. Compounds 3-6 are composed on trinuclear carboxylate units {Mg3(RCOO)6}. In isostructural compounds 3-5, these units are linked to each other through carboxylate bridges to form polymer layers; in compound 6, these units are linked together to form a doubly-interpenetrated three-dimensional metal-organic framework.

Marakulin A.V. , Lysova A.A. , Samsonenko D.G. , Dorovatovskii P.V. , Lazarenko V.A. , Dybtsev D.N. , Fedin V.P.
New one-, two-, and three-dimensional metal-organic frameworks based on magnesium(II): synthesis and structure
Russian Chemical Bulletin. 2020. V.69. N2. P.360-368. DOI: 10.1007/s11172-020-2768-9 WOS Scopus OpenAlex

Маракулин А.В. , Лысова А.А. , Самсоненко Д.Г. , Дороватовский П.В. , Лазаренко В.А. , Дыбцев Д.Н. , Федин В.П.
Новые одно-, двух- и трехмерные металл-органические координационные полимеры на основе магния(II): синтез и структура
Известия Академии наук. Серия химическая. 2020. №2. С.360-368. РИНЦ

Submitted:	Sep 3, 2019
Accepted:	Nov 18, 2019
Published online:	Apr 2, 2020

Web of science:	WOS:000523019700022
Scopus:	2-s2.0-85083105526
OpenAlex:	W3014759010

DB	Citing
OpenAlex	14
Scopus	13
Web of science	14