Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate Full article
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Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
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| Output data | Year: 2021, Volume: 66, Number: 9, Pages: 1374-1379 Pages count : 6 DOI: 10.1134/s0036023621090035 | ||||||
| Tags | cadmium complexes, metal-organic coordination polymer, octafluorobiphenyl-4,4'-dicarboxylic acid, crystal structure | ||||||
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Abstract:
The reaction between equimolar amounts of Cd(OH)2 and octafluorobiphenyl-4,4'-dicarboxylic acid H2oFBPDC in methanol at 40 and 70°С has been investigated. Two new metal-organic coordination polymers have been obtained and structurally characterized, namely chain-like [Cd3(CH3OH)10(oFBPDC)3]⋅2CH3OH (I) and layered [Cd(CH3OH)3(oFBPDC)] (II). It is shown that the increase of the temperature of the synthesis leads to the formation of coordination polymer of higher dimensionality with less amount of guest and coordinated solvent molecules.
Cite:
Gusarov V.S.
, Cheplakova A.M.
, Samsonenko D.G.
, Vinogradov A.S.
, Fedin V.P.
Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate
Russian Journal of Inorganic Chemistry. 2021. V.66. N9. P.1374-1379. DOI: 10.1134/s0036023621090035 WOS Scopus OpenAlex
Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate
Russian Journal of Inorganic Chemistry. 2021. V.66. N9. P.1374-1379. DOI: 10.1134/s0036023621090035 WOS Scopus OpenAlex
Original:
Гусаров В.С.
, Чеплакова А.М.
, Самсоненко Д.Г.
, Виноградов А.С.
, Федин В.П.
Синтез и кристаллическая структура металл-органических координационных полимеров на основе Cd(II) и октафторбифенил-4,4'-дикарбоксилата
Журнал неорганической химии. 2021. Т.66. №9. С.1280-1286. DOI: 10.31857/s0044457x21090038 OpenAlex
Синтез и кристаллическая структура металл-органических координационных полимеров на основе Cd(II) и октафторбифенил-4,4'-дикарбоксилата
Журнал неорганической химии. 2021. Т.66. №9. С.1280-1286. DOI: 10.31857/s0044457x21090038 OpenAlex
Dates:
| Submitted: | Mar 29, 2021 |
| Accepted: | Apr 20, 2021 |
| Published online: | Sep 21, 2021 |
Identifiers:
| Web of science: | WOS:000698438100008 |
| Scopus: | 2-s2.0-85115202148 |
| OpenAlex: | W3201031881 |