CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS

CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2021, Volume: 62, Number: 6, Pages: 897-904 Pages count : 8 DOI: 10.1134/s0022476621060093

Authors

Cherezova S.V. ^1,2 , Barsukova M.O. ¹ , Samsonenko D.G. ¹ , Fedin V.P. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.

Cherezova S.V. , Barsukova M.O. , Samsonenko D.G. , Fedin V.P.
CRYSTAL STRUCTURE OF DENSE METAL-ORGANIC FRAMEWORKS BASED ON Sc(III) AND TWO TYPES OF LIGANDS
Journal of Structural Chemistry. 2021. V.62. N6. P.897-904. DOI: 10.1134/s0022476621060093 WOS Scopus OpenAlex

Черезова С.В. , Барсукова М.О. , Самсоненко Д.Г. , Федин В.П.
Кристаллическая структура плотных металл-органических координационных полимеров на основе Sc(III) и двух типов лигандов
Журнал структурной химии. 2021. Т.62. №6. С.966-973. DOI: 10.26902/jsc_id74427 OpenAlex

Submitted:	Dec 23, 2020
Accepted:	Jan 18, 2021
Published online:	Jun 25, 2021

Web of science:	WOS:000667904000009
Scopus:	2-s2.0-85111112183
OpenAlex:	W3176084884

DB	Citing
OpenAlex	7
Scopus	5
Web of science	6