Реферат: A mechanistic study of direct selective oxidation of benzylic C(sp3)−H groups with peracetic acid, catalyzed by palladium complexes with tripodal amino-tris(pyriylmethyl) ligands, is presented. The oxidation of arylalkanes having secondary and tertiary benzylic C−H groups, predominantly yields, depending on the substrate and conditions, either the corresponding ketones or alcohols. One of the three 2-pyriylmethyl moieties, which is pending in the starting catalyst, apparently, facilitates the active species formation and takes part in stabilization of the high-valent Pd center in the active species, occupying the axial coordination site of palladium. The catalytic, as well as isotopic labeling experiments, in combination with ESI-MS data and DFT calculations, point out palladium oxyl species as possible catalytically active sites, operating essentially via C−H abstraction/oxygen rebound pathway. For the ketones formation, O−H abstraction/в-scission mechanism has been proposed.

Библиографическая ссылка: Lubov D.P. , Bryliakova A.A. , Samsonenko D.G. , Sheven D.G. , Talsi E.P. , Bryliakov K.P.
Palladium‐Aminopyridine Catalyzed C−H Oxygenation: Probing the Nature of Metal Based Oxidant
Chemcatchem. 2021. V.13. N24. P.5109-5120. DOI: 10.1002/cctc.202101345 WOS Scopus OpenAlex

Даты:

Поступила в редакцию:	8 сент. 2021 г.
Принята к публикации:	30 сент. 2021 г.
Опубликована online:	30 сент. 2021 г.
Опубликована в печати:	5 нояб. 2021 г.

Идентификаторы БД:

Web of science:	WOS:000714551600001
Scopus:	2-s2.0-85118583343
OpenAlex:	W3203361724

Цитирование в БД:

БД	Цитирований
OpenAlex	6
Scopus	6
Web of science	6

Альметрики: