Synthesis, crystal structures, and luminescence properties of coordination polymers and a discrete complex of cadmium(ii) halides with 1-(1,2,4-triazol-1-yl)adamantane Full article
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Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Output data | Year: 2021, Volume: 70, Number: 5, Pages: 857-863 Pages count : 7 DOI: 10.1007/s11172-021-3159-6 | ||
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Abstract:
The reactions of 1-(1,2,4-triazol-1-yl)adamantane with cadmium(ii) chloride, bromide, and iodide were studied. The crystal structures of the synthesized coordination compounds were determined by single-crystal X-ray diffraction. Cadmium(ii) chloride and bromide form 1D coordination polymers, in which cadmium ions are bridged by two halide ions, whereas cadmium(ii) iodide forms a discrete complex with a tetrahedral environment of the cadmium ion. in all compounds, the organic ligand is coordinated in a monodentate fashion through nitrogen atoms at the 4 positions of the 1,2,4-triazole rings. The quantum yield of ligand-centered luminescence of the halide complexes increases in the series of halogens from chlorine to iodine and reaches 35% for the iodide complex
Cite:
Pavlov D.I.
, Ryadun A.A.
, Samsonenko D.G.
, Fedin V.P.
, Potapov A.S.
Synthesis, crystal structures, and luminescence properties of coordination polymers and a discrete complex of cadmium(ii) halides with 1-(1,2,4-triazol-1-yl)adamantane
Russian Chemical Bulletin. 2021. V.70. N5. P.857-863. DOI: 10.1007/s11172-021-3159-6 WOS Scopus OpenAlex
Synthesis, crystal structures, and luminescence properties of coordination polymers and a discrete complex of cadmium(ii) halides with 1-(1,2,4-triazol-1-yl)adamantane
Russian Chemical Bulletin. 2021. V.70. N5. P.857-863. DOI: 10.1007/s11172-021-3159-6 WOS Scopus OpenAlex
Original:
Павлов Д.И.
, Рядун А.А.
, Самсоненко Д.Г.
, Федин В.П.
, Потапов А.С.
Синтез, кристаллическая структура и люминесцентные свойства координационных полимеров и дискретного комплекса галогенидов кадмия(II) с 1-(1,2,4-триазол-1-ил)адамантаном
Известия Академии наук. Серия химическая. 2021. №5. С.857-863.
Синтез, кристаллическая структура и люминесцентные свойства координационных полимеров и дискретного комплекса галогенидов кадмия(II) с 1-(1,2,4-триазол-1-ил)адамантаном
Известия Академии наук. Серия химическая. 2021. №5. С.857-863.
Dates:
| Submitted: | Dec 15, 2020 |
| Accepted: | Feb 1, 2021 |
| Published online: | Jun 2, 2021 |
Identifiers:
| Web of science: | WOS:000657311100007 |
| Scopus: | 2-s2.0-85107072084 |
| OpenAlex: | W3170691222 |