Реферат: Rational design of a series of new heterometallic MOFs was carried out by the judicious choice of the corresponding synthesis conditions and ligand geometry. Three heterometallic MOFs (H2NMe2)[LiZn(dmf)(tdc)2]·DMF·H2O (1), [{LiZn}2Li2Zn2(dmf)6(tdc)6]·6DMF·H2O (2) and [Li2Zn2(dmf)2(fdc)3]·2DMF·2H2O (3) were obtained on the basis of the pre-synthesized pivalate complex [Li2Zn2(py)2(piv)6]. The angle between carboxylic groups greatly affects the possibility of retaining the initial tetranuclear node in the structure of the obtained MOFs. Compound 3 demonstrates permanent porosity with a calculated BET surface area value of 287 m2 g−1. Compounds 2 and 3 are capable of heavy metal sorption from their nitrate solution, and a significant flare-up of the luminescence of the obtained inclusion compounds is observed, where the quantum yield of luminescence increases by an order of magnitude in the case of cadmium inclusion.

Библиографическая ссылка: Sapianik A.A. , Barsukova M.O. , Kovalenko K.A. , Samsonenko D.G. , Fedin V.P.
Heterometallic MOFs constructed from thiophene and furandicarboxylate ligands for heavy metal luminescence sensing
Dalton Transactions. 2021. V.50. N8. P.2807-2814. DOI: 10.1039/d0dt04047a WOS Scopus OpenAlex

Даты:

Поступила в редакцию:	26 нояб. 2020 г.
Принята к публикации:	12 янв. 2021 г.
Опубликована online:	14 янв. 2021 г.
Опубликована в печати:	28 февр. 2021 г.

Идентификаторы БД:

Web of science:	WOS:000624242900013
Scopus:	2-s2.0-85101977395
OpenAlex:	W3120111214

Цитирование в БД:

БД	Цитирований
OpenAlex	12
Scopus	12
Web of science	12

Альметрики: