Tailoring heterometallic cluster functional building blocks: synthesis, separation, structural and DFT studies of [Re6-xMoxSe8(CN)6]n-

Tailoring heterometallic cluster functional building blocks: synthesis, separation, structural and DFT studies of [Re6-xMoxSe8(CN)6]n- Full article

Journal

Chemistry: A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765

Output data

Year: 2019, Volume: 25, Number: 66, Pages: 15040-15045 Pages count : 6 DOI: 10.1002/chem.201903321

Authors

Muravieva V.K. ^1,2 , Gayfulin Y.M. ¹ , Prestipino C. ² , Lemoine P. ² , Ryzhikov M.R. ^1,3 , Yanshole V.V. ^3,4 , Cordier S. ² , Naumov N.G. ^1,3

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS
2	Institut des Sciences Chimiques de Rennes
3	Novosibirsk State University
4	International Tomography Center SB RAS

Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6-xMoxSe8(CN)6]n- (x = 2, 3; n = 4, 5) were obtained as individual salts. Their isomeric composition and bond lengths distribution were inspected using a combination of single-crystal X-ray structure analysis, NMR, EXAFS and DFT calculations.

Muravieva V.K. , Gayfulin Y.M. , Prestipino C. , Lemoine P. , Ryzhikov M.R. , Yanshole V.V. , Cordier S. , Naumov N.G.
Tailoring heterometallic cluster functional building blocks: synthesis, separation, structural and DFT studies of [Re6-xMoxSe8(CN)6]n-
Chemistry: A European Journal. 2019. V.25. N66. P.15040-15045. DOI: 10.1002/chem.201903321 WOS Scopus РИНЦ OpenAlex

Published online:

Aug 29, 2019

Web of science:	WOS:000492072800001
Scopus:	2-s2.0-85074595795
Elibrary:	43210610
OpenAlex:	W2970336468

DB	Citing
OpenAlex	10
Web of science	9
Scopus	11
Elibrary	5