SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE Full article
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2023, Volume: 64, Number: 2, Pages: 199-207 Pages count : 9 DOI: 10.1134/s002247662302004x | ||||
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Funding (1)
| 1 | Russian Science Foundation | 22-23-20179 |
Abstract:
The first example of a coordination polymer with a triply charged metal ion is obtained based on the conformationally mobile bridging ligand 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco). Its structure is characterized by single crystal X-ray diffraction. The compound has the formula [La(odabco)3]Cl3·xH2O (1) with a variable hydration number and is composed of six-coordinated octahedral La3+ sites. The 3D cationic coordination lattice of 1 has a primitive cubic (pcu) topology and contains isolated voids with a total specific volume of 28% filled with chloride anions and water molecules. The compound is characterized by powder XRD and elemental analysis. The absence of absorption maxima in the visible and UV ranges up to 270 nm is shown by diffuse reflectance spectroscopy for 1.
Cite:
Demakov P.A.
, Ovchinnikova A.A.
, Fedin V.P.
SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE
Journal of Structural Chemistry. 2023. V.64. N2. P.199-207. DOI: 10.1134/s002247662302004x WOS Scopus OpenAlex
SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE
Journal of Structural Chemistry. 2023. V.64. N2. P.199-207. DOI: 10.1134/s002247662302004x WOS Scopus OpenAlex
Original:
ДЕМАКОВ П.А.
, ОВЧИННИКОВА А.А.
, ФЕДИН В.П.
СИНТЕЗ, СТРОЕНИЕ И ОПТИЧЕСКИЕ СВОЙСТВА КАТИОННОГО КООРДИНАЦИОННОГО ПОЛИМЕРА ЛАНТАНА(III) С N,N'-ДИОКСИДОМ 1,4-ДИАЗАБИЦИКЛО[2.2.2]ОКТАНА
Журнал структурной химии. 2023. Т.64. №2. 105634 . DOI: 10.26902/JSC_id105634 РИНЦ
СИНТЕЗ, СТРОЕНИЕ И ОПТИЧЕСКИЕ СВОЙСТВА КАТИОННОГО КООРДИНАЦИОННОГО ПОЛИМЕРА ЛАНТАНА(III) С N,N'-ДИОКСИДОМ 1,4-ДИАЗАБИЦИКЛО[2.2.2]ОКТАНА
Журнал структурной химии. 2023. Т.64. №2. 105634 . DOI: 10.26902/JSC_id105634 РИНЦ
Dates:
| Published print: | Mar 9, 2023 |
| Published online: | Mar 9, 2023 |
Identifiers:
| Web of science: | WOS:000948838900004 |
| Scopus: | 2-s2.0-85149836523 |
| OpenAlex: | W4323659073 |