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Bismuth and antimony halometalates containing photoswitchable ruthenium nitrosyl complexes Научная публикация

Журнал Dalton Transactions
ISSN: 1477-9234 , E-ISSN: 1477-9226
Вых. Данные Год: 2023, Том: 52, Номер: 4, Страницы: 919-927 Страниц : 9 DOI: 10.1039/d2dt03497b
Авторы Mikhailov Artem A. 1 , Korobeynikov Nikita A. 2 , Usoltsev Andrey N. 2 , Adonin Sergey A. 2 , Kostin Gennadiy A. 2 , Schaniel Dominik 1
Организации
1 Université de Lorraine, CNRS, CRM2, UMR 7036, Nancy 54000, France
2 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Avenue, Novosibirsk 630090, Russian Federation

Информация о финансировании (3)

1 Министерство науки и высшего образования Российской Федерации 121031700313-8
2 Министерство науки и высшего образования Российской Федерации 121031700315–2
3 Российский научный фонд 22-43-09001

Реферат: The first examples of Bi(III) and Sb(III) halide compounds combined with a photoswitchable ruthenium nitrosyl unit are reported. The structures of [RuNOPy4Br]4[Sb2Br8][Sb3Br12]2 (1) and (H3O)[RuNOPy4Br]4[Bi2Br9]3·3H2O (2) were determined by X-ray diffraction, and exhibit three different structural types of group 15 halometalates. Low-temperature IR-spectroscopy measurements reveal that the irradiation of 1 at 365 nm switches a stable Ru–NO (GS) unit to a metastable Ru–ON (MS1) linkage. Moreover, the light excitation of 2 at 365 or 405 nm induces the additional formation of a side-bond isomer Ru-η2-(NO) (MS2). The reverse reactions MS1/MS2 → GS can be induced by red–infrared light irradiation or by heating at temperatures >200 K. The obtained synthetic and spectroscopic data open the way for the preparation of hybrid halide complexes with a variety of photoswitchable complexes (NO2, SO2, N2, etc.), and give an insight into the behavior of light-induced species embedded in polynuclear halides.
Библиографическая ссылка: Mikhailov A.A. , Korobeynikov N.A. , Usoltsev A.N. , Adonin S.A. , Kostin G.A. , Schaniel D.
Bismuth and antimony halometalates containing photoswitchable ruthenium nitrosyl complexes
Dalton Transactions. 2023. V.52. N4. P.919-927. DOI: 10.1039/d2dt03497b WOS Scopus OpenAlex
Даты:
Поступила в редакцию: 28 окт. 2022 г.
Принята к публикации: 19 дек. 2022 г.
Опубликована online: 19 дек. 2022 г.
Опубликована в печати: 5 янв. 2023 г.
Идентификаторы БД:
Web of science: WOS:000906748800001
Scopus: 2-s2.0-85145862448
OpenAlex: W4313407240
Цитирование в БД:
БД Цитирований
OpenAlex 4
Web of science 5
Scopus 5
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