Cadmium(II)-Organic Coordination Polymer Containing Carboxyl Groups: Solvothermal Synthesis, Structure, and Properties Full article
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Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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| Output data | Year: 2023, Volume: 49, Number: 12, Pages: 771-776 Pages count : 6 DOI: 10.1134/S1070328423600316 | ||||||
| Tags | metal-organic coordination polymers, XRD, polycarboxylate ligands, cadmium(II) complexes, luminescence | ||||||
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Abstract:
New metal-organic coordination polymer Cd[H2L] (I) (where H4L is 4,4'-([2,2'-bipyridine]-6,6'-diylbis(oxy))diphthalic acid) is synthesized in a high yield under the solvothermal synthesis conditions. According to the X-ray diffraction (XRD) data, each Cd(II) cation binds four organic ligands: one ligand is bound via the coordination of the chelate bipyridyl fragment, two ligands are linked via the bidentate coordination of the deprotonated COO groups, and one ligand is bound via the monodentate coordination of the protonated carboxylate group. The synthesized three-dimensional metal-organic framework contains no free space capable of including guest molecules. Compound I is characterized by powder XRD, IR spectroscopy, and elemental (C, H, N) and thermogravimetric analyses. The luminescence spectra of compound I are recorded.
Cite:
Xu B.
, Yao W.
, Yu X.
, Samsonenko D.G.
, Fedin V.P.
, Gao E.
Cadmium(II)-Organic Coordination Polymer Containing Carboxyl Groups: Solvothermal Synthesis, Structure, and Properties
Russian Journal of Coordination Chemistry. 2023. V.49. N12. P.771-776. DOI: 10.1134/S1070328423600316 WOS Scopus РИНЦ OpenAlex
Cadmium(II)-Organic Coordination Polymer Containing Carboxyl Groups: Solvothermal Synthesis, Structure, and Properties
Russian Journal of Coordination Chemistry. 2023. V.49. N12. P.771-776. DOI: 10.1134/S1070328423600316 WOS Scopus РИНЦ OpenAlex
Original:
Сюй Б.
, Яо В.
, Юй С.
, Самсоненко Д.Г.
, Федин В.П.
, Гао Э.
Сольвотермальный синтез, структура и свойства кадмий(II)-органического координационного полимера, содержащего карбоксильные группы
Координационная химия. 2023. Т.49. №12. С.731-736.
Сольвотермальный синтез, структура и свойства кадмий(II)-органического координационного полимера, содержащего карбоксильные группы
Координационная химия. 2023. Т.49. №12. С.731-736.
Dates:
| Submitted: | Feb 14, 2023 |
| Accepted: | Mar 13, 2023 |
| Published print: | Dec 1, 2023 |
Identifiers:
| Web of science: | WOS:001127497900005 |
| Scopus: | 2-s2.0-85180127946 |
| Elibrary: | 64365469 |
| OpenAlex: | W4389950211 |